The accordion list below identifies common peroxide forming chemicals and groups them by hazard class. This list should be used as a screening tool when reviewing laboratory inventories, evaluating chemical storage conditions, or determining whether additional testing or disposal may be needed.

Because peroxide hazards vary by chemical, concentration, storage age, inhibitor status, and use conditions, laboratories should not rely on the list alone to determine safety. Review the supporting peroxide forming chemical safety resources above and contact Environmental Health & Safety for assistance before handling any questionable, expired, damaged, crystallized, or potentially unstable container.

Important Handling Practices:
All peroxidizable chemicals and other materials that may become unstable over time must be clearly dated upon receipt and upon opening. These chemicals should be tested regularly for peroxide formation in accordance with the manufacturer’s instructions or institutional guidelines. Chemicals must be disposed of within 12 months of receipt or by the manufacturer’s expiration date, whichever comes first. Any chemical that tests positive for peroxide formation or exceeds recommended storage duration should be promptly disposed of through Environmental Health & Safety (EHS) procedures.

 

Butadiene (liquid monomer)Isopropyl etherSodium amide (sodamide)
Chloroprene (liquid monomer)Potassium amideTetrafluoroethylene (liquid monomer)
Divinyl etherPotassium metalVinylidene chloride
AcetalDicyclopentadieneMethyl isobutyl ketone
Acetaldehyde

Diethyl ether (ether)

 

4-Methyl-2-pentanol
Benzyl alcoholDioxanes2-Pentanol
2-Butanol

Ethylene glycol ether acetates (glyme)

 

4-Penten-1-ol
CumeneFuran1-Phenylethanol
Cyclohexanol4-HeptanolTetrahydrofuran (THF)
Cyclohexene2-Hexanol

Tetrahydronaphthalene (tetralin)

 

2-Cyclohexen-1-olMethylacetylene (gas)Vinyl ethers
Decahydronaphthalene (decalin)3-Methyl-1-butanol

Other secondary alcohols

 

Diacetylene (butadine, gas)Methyl cyclopentane 
Acrylic acidStyrene
AcrylonitrileTetrafluoroethylene (gas)
Butadiene (gas)

Vinyl acetate

 

Chlorobutadiene

Vinylacetylene (gas)

 

Chloroprene

 

Vinyladiene chloride

Chlorotrifluoroethylene (gas)Vinyl chloride (gas)

Methyl methacrylate

 

Vinyl pyridine

 

Acroleinp-Chlorophenetole4,5-Hexadien-2-yn-1-ol
Allyl etherCyclooctenen-Hexyl ether
Allyl ethyl etherCyclopropyl methyl ethero.p-Iodophenetole
Allyl phenyl etherDiallyl etherIsoamyl benzyl ether
p-(n-Amyloxy)benzoyl chloridep-Di-n-butoxybenzeneIsoamyl ether
n-Amyl ether1,2-DibenzyloxyethaneIsobutyl vinyl ether
Benzyl n-butyl etherp-DibenzyloxybenzeneIsophorone
Benzyl ether1,2-Dichloroethyl ethyl etherb-Isopropoxyproprionitrile
Benzyl ethyl ether2,4-DichlorophenetoleIsopropyl-2,4,5-trichlorophenoxy acetate
Benzyl methyl etherDiethoxymethanen-Methylphenetole 
Benzyl-1-naphthyl ether2,2-Diethoxypropane2-Methyltetrahydrofuran 
1,2-Bis(2-chloroethoxyl)ethaneDiethyl ethoxymethylenemalonate3-Methoxy-1-butyl acetate 
Bis(2-ethoxyethyl) etherDiethyl fumarate2-Methoxyethanol 
Bis(2-(methoxyethoxy)ethyl) etherDiethyl acetal2-Methoxyethyl acetate 
Bis(2-chloroethyl) etherDiethylketene3-Methoxybutyl acetate
Bis(2-ethoxyethyl) adipateDiethoxybenzene (m-,o-,p-)2-methoxyethyl vinyl ether
Bis(2-methoxyethyl) carbonate1,2-DiethoxyethaneMethoxy-1,3,5,7-cyclooctatetraene
Bis(2-methoxyethyl) etherDimethoxymethaneb-Methoxyproprionitrile
Bis(2-methoxyethyl) phthalate1,1-Dimethoxyethanem-Nitrophenetole 
Bis(2-methoxymethyl) adipateDi(1-propynl) ether1-Octene
Bis(2-n-butoxyethyl) phthalateDi(2-propynl) etherOxybis(2-ethyl acetate)
Bis(2-phenoxyethyl) etherDi-n-propoxymethaneOxybis(2-ethyl benzoate)
Bis(4-chlorobutyl) ether1,2-Epoxy-3-isopropoxypropaneb,b-Oxydipropionitrile
Bis(chloromethyl) ether1,2-Epoxy-3-phenoxypropane1-Pentene
2-Bromomethyl ethyl etherp-EthoxyacetophenonePhenoxyacetyl chloride 
beta-Bromophenetole1-(2-Ethoxyethoxy) ethyl acetatea-Phenoxypropionyl chloride
o-Bromophenetole2-Ethoxyethyl acetatePhenyl-o-propyl ether
p-Bromophenetole(2-Ethoxyethyl)-a-benzoylp-Phenylphenetone
3-Bromopropyl phenyl ether1-Ethoxynaphthalenen-Propyl ether
tert-Butyl methyl ethero,p-Ethoxyphenyl isocyanaten-Propyl isopropyl ether
n-Butyl phenyl ether1-Ethoxy-2-propyneSodium 8-11-14-eicosatetraenoate
n-Butyl vinyl ether3-EthoxypropionitrileSodium ethoxyacetylide
Chloroacetaldehyde diethylacetal2-Ethylacrylaldehyde oximeTetrahydropyran
2-Chlorobutadiene 2-EthylbutanolTriethylene glycol diacetate
1-(2-Chloroethoxy)-2-phenoxyethaneEthyl-b-ethoxyproprionateTriethylene glycol dipropionate
ChloroethyleneEthylene glycol monomethyl ether1,3,3-Trimethoxypropene
Chloromethyl methyl ether2-Ethylhexanal1,1,2,3-Tetrachloro-1,3-butadiene
beta-ChlorophenetoleEthyl vinyl ether4-Vinyl cyclohexene
o-Chlorophenol2,5-Hexadiyn-1-olVinylene carbonate

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